https://www.thieme-connect.de/DOI/DOI?10.1055/s-1996-4390Synthesis of Racemic Ethanolamine Plasmalogen
Synthesis 1996; 1996(11): 1345-1349
Hans Rudolf Pfaendler*, Volker Weimar
*Institute of Organic Chemistry, University of Munich, Karlstrasse 23, D-80333 Munich, Germany, Fax +49(89)5902483; E-mail hrp@org.chemie.uni-muenchen.de
Racemic C12-ethanolamine plasmalogen 5b was prepared in high yield. The amino group was generated by selective reaction of azide 4b with polymeric triphenylphosphine followed by mild hydrolysis of the intermediate phosphine imine. A novel universal phosphorylation reagent 2-azidoethyl dichlorophosphate (7) was used.
plasmalogen - synthesis - ethanolamine-phospholipids - 2-azidoethyl dichlorophosphate - polymeric triphenylphosphine
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修改:liuchao FROM 219.234.148.*
FROM 219.234.148.*